Sheet glass product fabrication with growth-limited glass bump spacers

ABSTRACT

Methods of forming a sheet glass product comprising a plurality of growth-limited glass bump spacers. According to the methods, a glass pane of the sheet glass product is irradiated with laser radiation to locally heat the glass pane at a plurality of spacer localities and induce growth of a plurality of glass bump spacers in the glass pane. The growth of the plurality of glass bump spacers is limited by utilizing a growth-limiting plate comprising a scattering surface portion. The scattering surface portion of the growth-limiting plate mitigates damage to the growth-limiting plate and may also mitigate damage to the glass pane. Vacuum insulated glass products and systems for forming a growth-limited sheet glass product are also provided.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a divisional of U.S. patent application Ser. No.US13/482114 filed on May 29, 2012, the content of which is relied uponand incorporated herein by reference in its entirety, and the benefit ofpriority under 35 U.S.C. § 120 is hereby claimed.

FIELD

The present disclosure relates generally to vacuum-insulated glasswindows, and in particular to such windows that employ glass-bumpspacers.

BACKGROUND

Vacuum-insulated glass (VIG) windows typically consist of two or moreglass panes with an evacuated space there between. The evacuated spaceenhances thermal and noise insulating properties of the window, ascompared to ordinary glass windows. Spacers are typically placed betweenthe glass panes of such windows to maintain the aforementioned spacing.The spacers are typically discrete elements disposed and fixed betweenthe glass panes and can be made of aluminum, plastic, ceramic, or glass.

Commonly-assigned US Patent Application Pub. No. 2010/0107525 provides amethod of forming a VIG window where a plurality of glass bump spacersare integrally formed in a surface of one of the glass panes. Thespacers are formed in the glass pane in a laser growth process.

BRIEF SUMMARY

The present inventors have recognized that the aforementioned spacergrowth methodology can be enhanced by providing a scattering surface orscattering surface portion on a growth-limiting glass plate and byimparting properties of the scattering surface to a correspondingsurface of the glass bump spacer. Concepts related to the structuralfeatures of the various VIG products contemplated herein and the mannerin which a laser growth process can be executed to form glass bumpspacers can be readily gleaned from the teachings in the aforementionedUS Patent Application (Pub. No. 2010/0107525) the contents of where areincorporated herein by reference in their entirety. Nevertheless, it iscontemplated that although the concepts of the present disclosure aredescribed herein with primary reference to VIG glass products, such as,e.g., VIG glass windows, the concepts disclosed herein will enjoy broadapplicability to any application where an evacuated or non-evacuatedspacing is to be maintained between two opposing glass panes. It is alsocontemplated that the concepts disclosed herein will enjoy applicabilityto any laser-induced spacer growth process without limitation to theparticular processes and laser growth system disclosed in theaforementioned patent application.

According to one embodiment of the present disclosure, a method offorming a sheet glass product comprises a plurality of growth-limitedglass bump spacers. According to the method, a glass pane of the sheetglass product is irradiated with laser radiation to locally heat theglass pane at a plurality of spacer localities and induce growth of aplurality of glass bump spacers in the glass pane. The growth of theplurality of glass bump spacers is limited by utilizing agrowth-limiting plate comprising a scattering surface portion. Thescattering surface portion of the growth-limiting plate mitigates damageto the growth-limiting plate and may also mitigate damage to the glasspane.

According to another embodiment of the present disclosure, a system isprovided for forming a growth-limited sheet glass product comprising aplurality of growth-limited glass bump spacers. The system comprises anoptical system configured to irradiate a glass pane of the sheet glassproduct with laser radiation to locally heat the glass pane at aplurality of spacer localities and induce growth of a plurality of glassbump spacers in the glass pane. A growth-limiting plate is also providedand comprises the aforementioned scattering surface portion.

According to yet another embodiment of the present disclosure a vacuuminsulated glass product is provided where the respective contactsurfaces of the glass bump spacers comprise a scattering surface portionthat is configured for significant scattering of ultraviolet or infraredlaser light.

BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

The following detailed description of specific embodiments of thepresent disclosure can be best understood when read in conjunction withthe following drawings, where like structure is indicated with likereference numerals and in which:

FIG. 1 illustrates a vacuum insulated glass product comprising opposingglass panes disposed opposite and substantially parallel to one another;

FIG. 2 illustrates one example of a contemplated glass bump spacerconfiguration according to the present disclosure;

FIGS. 3 and 5 illustrate contemplated methods of forming a glass bumpspacer; and

FIG. 4 illustrates the inventors' recognition that contemplatedlaser-induced growth processes can induce localized damage in aconventional growth-limiting glass plate.

DETAILED DESCRIPTION

Although the concepts disclosed herein will enjoy applicability to anyapplication where an evacuated or non-evacuated spacing is to bemaintained between two opposing glass panes, for the purposes ofillustration, reference is initially made to the VIG product 10illustrated in FIG. 1, which comprises opposing glass panes 20 disposedopposite and substantially parallel to one another. An edge seal 30 isprovided about the periphery of the glass panes 20 to define ahermetically sealed interior region 40 between the two glass panes 20.The sealed interior region 40 can be at least partially evacuated toprovide desirable thermal and acoustic insulation properties.

The illustrated VIG product 10 further includes a plurality ofglass-bump spacers 50 that are integrally formed in one or both of theglass panes 20. Although the size, scale, geometry, and general shape ofcontemplated glass bump spacers 50 can vary without departing from thescope of the present disclosure, FIG. 2 is presented to illustrate oneexample of a contemplated glass bump spacer configuration according tothe present disclosure. Contemplated glass bump spacers 50 areintegrally formed in the glass pane 20 and are not added as separate ordiscrete elements of the VIG product. Thus, the glass bump spacers 50are formed from, and thus consist of, essentially the same material asthe glass pane 20 and may be accurately described as extensions of thebody portion of the glass pane 20.

As is noted above, the disclosure of US Patent Application Pub. No.2010/0107525 presents a variety of suitable methods of forming glassbump spacers 50 in a glass pane. Generally, referring to FIG. 3,contemplated methods of forming glass bump spacers 50 will employ one ormore mid-infrared-wavelength lasers, one or more high repetition-rate,nanosecond-pulse-width UV lasers, or combinations thereof, includingother types of laser sources, and suitable optics 60 to focus a laserradiation 70 in the form of a laser beam at a focal point that isaxially displaced slightly, e.g., approximately 0.8 mm to approximately1.0 mm, beyond the glass pane in which the spacer 50 is to be formed.This focused laser radiation 70 makes it possible to locally heat theglass pane 20 to its working temperature and enable the formation of theglass-bump spacer 50.

More specifically, a portion of the laser radiation 70 is absorbed as itpasses through the glass pane 20. This absorption serves to locally heatthe glass pane, forming a limited expansion zone within the glass pane20. It is worth noting that glass within the aforementioned expansionzone will, in many cases, melt and flow, as opposed to simply expanding.Since the expansion zone is constrained by unheated, and thereforeunexpanded, regions of glass surrounding the expansion zone, the glasswithin the expansion zone is compelled to relieve internal stresses bymelting, flowing, expanding, or otherwise growing upward, therebyforming a glass bump spacer 50. The spacer 50 can be fixed by rapidlycooling the heated region of the glass pane 20. In one contemplatedembodiment, this fixing is accomplished by merely terminating the laserirradiation. Referring further to FIG. 3, a growth-limiting surface inthe form of a glass plate 80 can be placed adjacent the glass pane 20during glass bump spacer growth to limit growth of the glass bump spacer50 to a certain bump height. The resulting glass-bump spacer 50 willhave a substantially flat top portion, which is illustrated in detail inFIG. 2.

Referring to FIG. 4, the present inventors have recognized thatcontemplated laser-induced growth processes can induce localized damage90 in a conventional growth-limiting glass plate 80′, which is typicallyhighly transparent to the laser irradiation. Further, this localizeddamage 90 can induce localized cracking in the glass pane 20 in which aglass bump spacer 50 is grown. More specifically, bump growthexperiments were carried out on 2-3 mm thick soda-lime glass using a12-14 W laser beam and 0.3 s exposure. Localized damage 90 in thegrowth-limiting fused silica plate and fracturing of the soda-lime glasspane were observed. It is believed that the damage in thegrowth-limiting plate was caused by progressively tighter focusing inthe glass bump spacer as growth progressed. In effect, the growing bumpacted as a lens with a relatively small focal distance, leading to laserbeam focusing inside the growth-limiting plate. Further, it iscontemplated that damage may also have been induced in the glass pane asa portion of the irradiating laser beam was reflected from the incidentsurface of the growth-limiting plate and focused inside the soda-limeglass pane. Finally, it is contemplated that the localized damageinduced in the growth-limiting plate initiated cracking in the soda-limeglass pane in which the bump was being grown.

As is illustrated in FIGS. 3 and 5, the various sources ofaforementioned damage to the growth-limiting plate 80 and the glass pane20 can be mitigated by utilizing a scattering surface or scatteringsurface portion 85 on the growth-limiting side of the growth limitingglass plate 80 to inhibit laser beam focusing inside the growth-limitingplate 80 and to prevent the refocusing of reflected light back into theglass pane 20.

More specifically, according to the embodiment of the present disclosureillustrated in FIGS. 3 and 5, the growth of the plurality of glass bumpspacers 50 is limited by utilizing a growth-limiting plate 80 thatcomprises a scattering surface portion 85 positioned in the optical pathof the laser radiation 70. As is illustrated schematically in FIG. 3,the optical path extends from a source of the laser radiation, throughthe glass pane 20, to the scattering surface portion 85 of thegrowth-limiting plate 80. The scattering surface portion 85 of thegrowth-limiting plate 80 is designed to scatter the laser radiation thatis used to locally heat the glass pane and may be presented in a varietyof forms. For the purposes of defining and describing the concepts ofthe present disclosure, it is noted that “significant” scattering isunderstood to mean a degree of scattering that would mitigate at least amajority of the aforementioned damage to the glass pane 20 orgrowth-limiting plate 80.

Referring collectively to FIGS. 1 and 2, the glass bump spacers 50extend across the interior region defined between the opposing glasspanes 20 to define respective contact surfaces against which a face ofone of the opposing glass panes 20 rests. It is contemplated that theglass bump spacers 50 can be integrally formed in one or both of theopposing glass panes 20. In either case, the opposing glass pane willrest against a contact surfaces of a glass bump spacer 50, if therespective spacer heights and glass pane planarity are controlledproperly. The respective contact surfaces of the glass bump spacers 50will comprise a complementary scattering surface portion 55 because theglass bump spacers come into contact with the scattering surface portion85 of the growth-limiting plate 80 during the growth process. As such,the optical and mechanical properties of the complementary scatteringsurface portion 55 will mimic that of the scattering surface portion 85of the growth-limiting plate 80. In particular, it is contemplated thatthe scattering surface portion 55 may also help reduce mechanical stressat the plane of contact defined between the scattering surface portion55 of the spacer 50 and a corresponding surface of an opposing glasspane 20.

For example, and not by way of limitation, the growth-limiting plate 80may comprise a borosilicate or fused silica glass plate and thescattering surface portion may be presented as a ground surface portionof the plate. Alternatively, the scattering surface portion may bepresented by providing an optically engineered scattering surface on thegrowth-limiting plate 80, which surface may be applied to or integrallyformed in a surface of the growth-limiting plate 80. Examples ofoptically engineered scattering surfaces include, but are not limitedto, mechanically ground, etched, or leeched surfaces. In instances wherethe present disclosure refers to a particular structure as a “plate,” itis noted that the “plate” need not be a uniform, sheet-like structure.Rather, for the purposes of defining and describing concepts of thepresent disclosure, it is noted that a “plate” may comprise anystructure that presents a continuous or discontinuous, regular orirregular, flat or curved face.

In some contemplated embodiments of the present disclosure, the glasspane is irradiated with UV laser radiation to induce growth of theplurality of glass bump spacers 50 in the glass pane 20 and thescattering surface portion 85 of the growth-limiting surface isconfigured for significant scattering of UV laser radiation.Contemplated UV wavelengths for effective growth and scattering liebetween about 340 nm and about 380 nm. In other contemplated embodimentsof the present disclosure, the glass pane is irradiated with IR laserradiation to induce growth of the plurality of glass bump spacers 50 inthe glass pane 20 and the scattering surface portion 85 of thegrowth-limiting surface is configured for significant scattering of IRlaser radiation. Contemplated IR wavelengths for effective growth andscattering lie between about 800 nm and about 1600 nm.

For the purposes of describing and defining the present disclosure, itis noted that recitations herein of “at least one” component, element,etc., should not be used to create an inference that the alternative useof the articles “a” or “an” should be limited to a single component,element, etc. It is noted that recitations herein of a component of thepresent disclosure being “configured” in a particular way, to embody aparticular property, or to function in a particular manner, arestructural recitations, as opposed to recitations of intended use. Morespecifically, the references herein to the manner in which a componentis “configured” denotes an existing physical condition of the componentand, as such, is to be taken as a definite recitation of the structuralcharacteristics of the component.

It is noted that terms like “preferably,” “commonly,” and “typically,”when utilized herein, are not utilized to limit the scope of the claimeddisclosure or to imply that certain features are critical, essential, oreven important to the structure or function of the claims. Rather, theseterms are merely intended to identify particular aspects of anembodiment of the present disclosure or to emphasize alternative oradditional features that may or may not be utilized in a particularembodiment of the present disclosure.

For the purposes of describing and defining the present embodiments itis noted that the terms “substantially,” “approximately,” and “about”are utilized herein to represent the inherent degree of uncertainty thatmay be attributed to any quantitative comparison, value, measurement, orother representation. The terms “substantially,” “approximately,” and“about” are also utilized herein to represent the degree by which aquantitative representation may vary from a stated reference withoutresulting in a change in the basic function of the subject matter atissue.

Having described the subject matter of the present disclosure in detailand by reference to specific embodiments thereof, it is noted that thevarious details disclosed herein should not be taken to imply that thesedetails relate to elements that are essential components of the variousembodiments described herein, even in cases where a particular elementis illustrated in each of the drawings that accompany the presentdescription. Rather, the claims appended hereto should be taken as thesole representation of the breadth of the present disclosure and thecorresponding scope of the various embodiments described herein.Further, it will be apparent that modifications and variations arepossible without departing from the scope of the disclosure defined inthe appended claims. More specifically, although some aspects of thepresent disclosure are identified herein as preferred or particularlyadvantageous, it is contemplated that the present disclosure is notnecessarily limited to these aspects.

It is noted that one or more of the following claims utilize the term“wherein” as a transitional phrase. It is noted that this term isintroduced in the claims as an open-ended transitional phrase that isused to introduce a recitation of a series of characteristics of thestructure and should be interpreted in like manner as the more commonlyused open-ended preamble term “comprising.”

What is claimed is:
 1. A vacuum insulated glass product comprisingopposing glass panes and an edge seal, wherein: the opposing glass panesare disposed in a spaced relation opposite and substantially parallel toeach other to define an interior region there between; the edge seal isdisposed about a periphery of the glass panes to hermetically seal theinterior region defined between the opposing glass panes; at least oneof the glass panes comprises a plurality of glass bump spacersintegrally formed therein; the glass bump spacers extend across theinterior region defined between the opposing glass panes and eachcomprise a glass contact surface against which a face of one of theopposing glass panes rests; and the glass contact surface of at leastone of the glass hump spacers comprises a glass scattering surfaceportion that is integrally formed with the glass contact surface and theat least one of the glass bump spacer and configured for significantscattering of ultraviolet or infrared laser light.
 2. The product asclaimed in claim 1 wherein the glass scattering surface portion of theat least one glass bump spacer is configured for significant scatteringof UV laser radiation.
 3. The product as claimed in claim 1 wherein theglass scattering surface portion of the at least one glass bump spaceris configured for significant scattering of laser radiation betweenabout 340 nm and about 380 nm.
 4. The product as claimed in claim 1wherein the glass scattering surface portion of the at least one glassbump spacer is for significant scattering of IR laser radiation.
 5. Theproduct as claimed in claim 1 wherein the glass scattering surfaceportion of the at least one glass bump spacer is configured forsignificant scattering of laser radiation between about 800 nm and about1600 nm.
 6. The product as claimed in claim 1 wherein the vacuuminsulated glass product comprises more than one pair of opposing glasspanes.
 7. The product as claimed in claim 1 wherein: the glass bumpspacers are integrally formed in only one of the opposing glass panes;and the other of the opposing glass panes rests against the glasscontact surfaces of the glass bump spacers.
 8. The product as claimed inclaim 1 wherein: the glass bump spacers are integrally formed in both ofthe opposing glass panes; and both of the opposing glass panes restagainst respective glass contact surfaces of the glass bump spacers. 9.The product as claimed in claim 1 wherein the glass scattering surfaceportion of the at least one glass bump spacer comprises roughened glass.10. The product as claimed in claim 1 wherein the glass scatteringsurface portion is arranged only on the plurality of glass bump spacers.